Journal of the American Chemical Society

Temperature dependence of carbene-carbene rearrangements. A new method for the generation of carbenes

UH Brinker, J Ritzer

文献索引：Brinker, Udo H.; Ritzer, Joachim Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 2116 - 2119

被引用次数: 41

摘要

Acknowledgment. This investigation was supported by Grant CA 21 136, awarded by the National Cancer Institute. cleophilic enolate 4 would serve in the relatively unexplored role of an electrophile in the above reaction. Indeed, when the epoxy enolate 4 (G= Li) was treated with Me2CuLi and the resulting product subjected to acidic hydrolysis, 6- methylcyclohex-2-enone (8, R= Me), the product of sN2'attack, was obtained in 65% yield, ...

~61%

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~1%

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~51%

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~1%

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~48%

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~25%

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~0%

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~6%

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~5%

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~0%

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~12%

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~4%

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~1%

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~3%

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