Carbenes and the oxygen-hydrogen bond: 3-cyclopentenylidene. A novel approach to bis (homocyclopropenyl) cations

…, P Van Chiem, PG Henning

文献索引：Kirmse, Wolfgang; Chiem, Pham Van; Henning, Paul G. Journal of the American Chemical Society, 1983 , vol. 105, # 6 p. 1695 - 1696

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被引用次数: 26

摘要

01 2.3 x 26.OC "pH" as read with a glass electrode. The pHs were unchanged at the end of the reaction. Standard deviation within each run less than 1%; duplicate runs usually within 1%, with a few within 10%. than pyruvic acid. With a-oxovaleric acid as substrate, which is ca. 20% slower ... As Table I shows, all the pyridoxamines with basic side chains (10-16) show significant accelerations relative to pyridoxamine itself (7) or 9. However, the optimum catalysis ...