The wittig rearrangement of (diarylmethoxy) acetamides

C Van Der Stelt, WJ Heus…

文献索引：van der Stelt,C. et al. Recueil des Travaux Chimiques des Pays-Bas, 1973 , vol. 92, p. 493 - 512

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被引用次数: 5

摘要

Abstract N, N-Dialkyl-2-(arylmethoxy)-or N, N-dialkyl-2-(diarylmethoxy) acetamides were found to undergo a Wittig rearrangement under the influence of bases such as sodium hydride to form either N, N-dialkyl-3-aryl-or 3, 3-diaryllactamides. When the diarylmethoxy group was asymmetric, the rearrangement resulted in diastereoisomeric reaction products. Ortho substitution in one or both aryl rings altered the course of rearrangement with the ...