Chiral bicyclic phosphoramidites—A new class of ligands for asymmetric catalysis

O Huttenloch, J Spieler…

文献索引：Spieler, Jan; Huttenloch, Oliver; Waldmann, Herbert European Journal of Organic Chemistry, 2000 , # 3 p. 391 - 399

全文：HTML全文

被引用次数: 65

摘要

Abstract The development of new ligands for catalytic asymmetric C− C bond formation is of great interest to organic synthesis. We describe here a new class of chiral phosphoramidites that embody one or two binaphthol units attached to an achiral azabicyclic [3.3. 1] or [3.3. 0] framework. These ligands were easily accessible from (R)-1, 1′-binaphthyl-2, 2′- dioxaphosphorchloridite (4) and the corresponding heterobicyclic core 1, 2, or 3. They ...

~83%

~87%

Bispidine as a secondary structure nucleator in peptides

[Haridas; Sadanandan, Sandhya; Sharma, Yogesh K.; Chinthalapalli, Srinivas; Shandilya, Ashutosh Tetrahedron Letters, 2012 , vol. 53, # 6 p. 623 - 626]

Synthesis and coordination chemistry of N, N-diallylbispidin...

[Cui, Huiling; Goddard, Richard; Poerschke, Klaus-Richard Organometallics, 2011 , vol. 30, # 22 p. 6241 - 6252]