Palladium-catalyzed reductive homocoupling of aromatic halides and oxidation of alcohols

…, Y Du, L Shao, C Qi, XM Zhang

文献索引：Zeng, Minfeng; Du, Yijun; Shao, Linjun; Qi, Chenze; Zhang, Xian-Man Journal of Organic Chemistry, 2010 , vol. 75, # 8 p. 2556 - 2563

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被引用次数: 42

摘要

Palladium-catalyzed reductive homocoupling of aromatic halides can be performed in alcohol solutions without any auxiliary reducing reagents. Pd (dppf) Cl2 [dppf= 1, 1′-bis (diphenylphosphino) ferrocene] has been shown as the most effective catalyst among the palladium catalysts screened for the model reductive homocoupling of iodobenzene in alcoholic solutions. The reduction of iodobenzene is stoichiometrically coupled with the ...