The Journal of Organic Chemistry

Preparation of 2-substituted arsabenzenes

AJ Ashe III, WT Chan

文献索引：Ashe,A.J.; Chan,W.-T. Journal of Organic Chemistry, 1979 , vol. 44, p. 1409 - 1413

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被引用次数: 26

摘要

A variety of 1.4-diynes react with dibutyltin hydride to give predominately 2-alkyl-l, l-dibutyl-1, 4-dihydrostan-nabenzenes. These may be readily Converted to 2-alkylarsabenzenes by treatment with arsenic trichloride. In this manner, 6-acetoxy-1, 4-hexadiyne has been converted to 2-arsabenzyl acetate and hence to a number of 2-functionalized arsabenzenes.