The Journal of Organic Chemistry

Preparation of 2-substituted arsabenzenes

AJ Ashe III, WT Chan

Index: Ashe,A.J.; Chan,W.-T. Journal of Organic Chemistry, 1979 , vol. 44, p. 1409 - 1413

Full Text: HTML

Citation Number: 26

Abstract

A variety of 1.4-diynes react with dibutyltin hydride to give predominately 2-alkyl-l, l-dibutyl-1, 4-dihydrostan-nabenzenes. These may be readily Converted to 2-alkylarsabenzenes by treatment with arsenic trichloride. In this manner, 6-acetoxy-1, 4-hexadiyne has been converted to 2-arsabenzyl acetate and hence to a number of 2-functionalized arsabenzenes.

Nickel-catalyzed decarboxylative coupling reaction of alkyny...

[Choe, Juseok; Yang, Jiyoung; Park, Kyungho; Palani, Thiruvengadam; Lee, Sunwoo Tetrahedron Letters, 2012 , vol. 53, # 51 p. 6908 - 6912]

Copper catalyzed regioselective coupling of allylic halides ...

[Bieber, Lothar W.; da Silva, Margarete F. Tetrahedron Letters, 2007 , vol. 48, # 40 p. 7088 - 7090]

Facile generation of a reactive palladium (II) enolate inter...

[Tsuda, Tetsuo; Chujo, Yoshiki; Nishi, Sei-ichi; Tawara, Kunio; Saegusa, Takeo Journal of the American Chemical Society, 1980 , vol. 102, # 20 p. 6381 - 6384]

Organocopper Compounds

[Bumagin, N. A.; Kalinovskii, I. O.; Ponomarev, A. B.; Beletskaya, I. P. Doklady Chemistry, 1982 , vol. 265, p. 262 - 266 Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 265, # 5 p. 1138 - 1143]