Journal of the American Chemical Society

Synthesis of Alkyl and Substituted Alkyl Fluorides from p-Toluenesulfonic Acid Esters. The Preparation of p-Toluenesulfonic Acid Esters of Lower Alcohols1

WF Edgell, L Parts

文献索引：Edgell; Parts Journal of the American Chemical Society, 1955 , vol. 77, p. 4899,4901

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被引用次数: 119

摘要

A number of alkyl and substituted alkyl fluorides has been prepared from the corresponding p-toluenesulfonic acid esters (tosylates) by reaction with potassium fluoride. Isomerization, extensive elimination and doubling of chain length, the common disadvantages of the reaction between alkyl halides and transition metal fluorides, were not encountered. The method constitutes a convenient and dependable laboratory synthesis of primary and ...