Journal of the American Chemical Society

Alkenylboranes. II. Improved preparative methods and new observations on methylvinylboranes

CD Good, DM Ritter

文献索引：Good, R. D.; Ritter, D. M. Journal of the American Chemical Society, 1962 , vol. 84, p. 1162 - 1166

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被引用次数: 112

摘要

Reaction of chlorovinylboranes with dimethyl zinc gave the itiethylviiiylboraiies and trivinylborane. disproportionation reaction gave chlorornethylvinylborane. Ultraviolet and nuclear magnetic resoiiance (t1. mr) spectra were observed. Bn approximate linear combination of atomic orbitals-molecular orbital (1. cao-no.) computation was used as a model to correlate the postulated delocalization with some of the physical properties.