Journal of the American Chemical Society

Alkenylboranes. II. Improved preparative methods and new observations on methylvinylboranes

CD Good, DM Ritter

Index: Good, R. D.; Ritter, D. M. Journal of the American Chemical Society, 1962 , vol. 84, p. 1162 - 1166

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Citation Number: 112

Abstract

Reaction of chlorovinylboranes with dimethyl zinc gave the itiethylviiiylboraiies and trivinylborane. disproportionation reaction gave chlorornethylvinylborane. Ultraviolet and nuclear magnetic resoiiance (t1. mr) spectra were observed. Bn approximate linear combination of atomic orbitals-molecular orbital (1. cao-no.) computation was used as a model to correlate the postulated delocalization with some of the physical properties.