Journal of Molecular Structure

Photolysis of allene-ozone mixtures at 647 nm in cryogenic matrices: Part 1. Formation of allene oxide

KA Singmaster, GC Pimentel

文献索引：Singmaster, Karen A.; Pimentel, George C. Journal of Molecular Structure, 1989 , vol. 194, p. 215 - 238

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被引用次数: 20

摘要

Abstract Matrix studies of the photolytic reaction at 647 nm between allene and ozone were carried out at 12 K. Primary photoproducts include carbon monoxide, acrolein (cis and trans), cyclopropanone, ketene, ethylene, allene oxide and formaldehyde. In Ar and Kr matrices both acrolein and cyclopropanone are produced in high yields, whereas in Xe matrices cyclopropanone is the major product. Infrared spectra for cyclopropanone and its ...