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Tetrahedron

Silver-catalyzed facile decarboxylation of coumarin-3-carboxylic acids

F Jafarpour, N Jalalimanesh, MBA Olia, AO Kashani

文献索引:Jafarpour, Farnaz; Jalalimanesh, Nafiseh; Olia, Mina Barzegar Amiri; Kashani, Asieh Otaredi Tetrahedron, 2010 , vol. 66, # 49 p. 9508 - 9511

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被引用次数: 16

摘要

A simple and highly efficient protocol with mild reaction conditions has been developed that allows the smooth protiodecarboxylation of diversely functionalized coumarin-3-carboxylic acids. In the presence of catalytic amounts of Ag2CO3 and acetic acid, even un-activated coumarin-3-carboxylic acids were converted in good to excellent yields and with great preparative ease to the corresponding coumarin derivatives.