Cation radicals as intermediates in aromatic halogenation with iodine monochloride: solvent and salt effects on the competition between chlorination and iodination
SM Hubig, W Jung, JK Kochi
文献索引：Hubig, S. M.; Jung, W.; Kochi, J. K. Journal of Organic Chemistry, 1994 , vol. 59, # 21 p. 6233 - 6244
Three distinct classes of substitutional reactivity can be discerned in the halogenation of a series of methyl-substituted methoxybenzenes (ArH) with iodine monochloride (ICl), namely, exclusive iodination, exclusive chlorination, and mixed iodinatiodchlorination. Spectral studies establish the prior formation of the charge-transfer complex [ArH, ICll which suffers electron transfer to afford the reactive triad [ArH+, I', C1-I according to Scheme 1. Separate ...
