Preparation, fluorination and synthetic utility of a CFC-olefin adduct

M Van Der Puy, TR Demmin, GVB Madhavan…

文献索引：Van Der Puy, Michael; Demmin, Timothy R.; Bindu Madhavan; Thenappan, Alagappan; Tung, Harry S. Journal of Fluorine Chemistry, 1996 , vol. 76, # 1 p. 49 - 54

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被引用次数: 8

摘要

1, 1, 1-Trichlorotrifluoroethane was added to ethylene using the catalyst system Fe/triethylphosphite, which eliminated the need for a solvent and avoided the corrosion problems inherent in CuCl-catalyzed reactions. The adduct, CF3CCl2CH2CH2Cl, was fluorinated with HF over a chromium (III) oxide catalyst. A series of alternating dehydrochlorinations and HF additions to internal C= C double bonds was proposed and ...