Palladium??Catalyzed Oxidative C C Bond Cleavage Cyclization of Biaryl??2??amines with Alkenes Involving C H Olefination and Carboamination

…, CY Wu, LB Gong, M Hu, ZQ Wang…

文献索引：Liu, Yan-Yun; Song, Ren-Jie; Wu, Cui-Yan; Gong, Lu-Bin; Hu, Ming; Wang, Zhi-Qiang; Xie, Ye-Xiang; Li, Jin-Heng Advanced Synthesis and Catalysis, 2012 , vol. 354, # 2-3 p. 347 - 353

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被引用次数: 25

摘要

Abstract A new, general method for the synthesis of phenanthridines has been developed by palladium-catalyzed oxidative remote C [BOND] H olefination–carboamination–C [BOND] C bond cleavage tandem reaction. It is noteworthy that alkenes are used as the one-carbon resources for this tandem reaction.

~64%

~61%

~36%

~35%

~40%

~30%

~24%

~27%

~27%

~22%

~19%

~19%

~21%

~19%

~22%

~13%

~56%

~5%

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