Tetrahedron

The Phenylthiocyclopropylsilyl Group: a Useful Latent Hydroxy Group

R Angelaud, Y Landais

文献索引：Angelaud, Remy; Landais, Yannick Tetrahedron, 2000 , vol. 56, # 14 p. 2025 - 2036

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被引用次数: 14

摘要

The α-dimethyl (1-phenylthio) cyclopropylsilyl group was used as a new masked hydroxy group. Three procedures have been devised to allow the oxidation of this silicon group in the presence of various functionalities. The desired alcohols are obtained in high yields with retention of configuration at the carbon centre.