Lewis Acid??Catalyzed Oxidative Allylation: A New Approach for the Synthesis of Homoallylic Alcohols and Amines Directly from Alcohols

VP Srivastava, R Patel…

文献索引：Srivastava, Vishnu P.; Patel, Rajesh; Yadav, Lal Dhar S. Advanced Synthesis and Catalysis, 2011 , vol. 353, # 5 p. 695 - 700

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被引用次数: 6

摘要

Abstract A new approach for the synthesis of homoallylic alcohols and amines directly from alcohols via one-pot sequential oxidation–Barbier reaction and oxidation–condensation– Barbier reactions, respectively, is reported. The protocol involves the one-pot ferric chloride- catalyzed oxidation of alcohols to the corresponding aldehydes with chloramine-T followed by indium-mediated Barbier allylation with allyl bromide to afford homoallylic alcohols in ...