Thermal decomposition of acetyl propionyl peroxide in acetone-d 6

ED Skakovskii, AI Stankevich, LY Tychinskaya…

文献索引：Skakovskii; Stankevich; Tychinskaya; Shirokii; Choban; Murashko; Rykov Russian Journal of General Chemistry, 2004 , vol. 74, # 11 p. 1719 - 1725

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被引用次数: 3

摘要

Abstract The kinetics of thermolysis of acetyl propinyl peroxide in acetone-d 6 in the temperature range 323–373 K was studied using NMR spectroscopy and the effect of chemically induced nuclear polarization. The peroxide decomposes in acetone at rates comparable with the rates of thermolysis in alcohols, yielding numerous products. In the examined temperature range, the solvent molecules act as efficient donors of deuterium ...