Journal of the American Chemical Society

Hydrogenation of ethylene over platinum (111) single-crystal surfaces

F Zaera, GA Somorjai

文献索引：Zaera, F.; Somorjai, G. A. Journal of the American Chemical Society, 1984 , vol. 106, # 8 p. 2288 - 2293

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被引用次数: 333

摘要

Abstract: The hydrogenation of ethylene with both hydrogen and deuterium was studied over (1 11) platinum single-crystal surfaces under a total pressure of 110 torr and a temperature range of 300-370 K. An activation energy (E,) of 10.8 f 0.1 kcal/mol and kinetic orders with respect to hydrogen and ethylene partial pressure of 1.31 f 0.05 and-0.60 f 0.05, respectively, were observed. The deuterium atom distribution in the product from the ...