A convenient synthetic route to (E)-2-penten-1-ol

AE Gastaminza, NN Ferracutti…

文献索引：Gastaminza, Alicia E.; Ferracutti, Nilda N.; Rodriguez, Nora M. Journal of Organic Chemistry, 1984 , vol. 49, # 20 p. 3859 - 3860

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被引用次数: 13

摘要

Concentrations about 25%(v/v), solvent CDC13. b. Metalation in Strongly Polar Medium. In the reaction flask (see a) was placed a solution of 0.11 mol of t-BuOK in 80 mL of THF, 0.20 mol of pyridine, and 40 mL of HMPT (dried by adding a sufficient quantity of a concentrated solution of lithium-3 g/100 mL-in liquid ammonia until the blue color persisted and subsequently distilling twice at 1+ 15 mmHg). The mixture was cooled to-105 to-110" C ...