Adamantylation of imidazoles and benzimidazole

GF Raenko, NI Korotkikh, TM Pekhtereva…

文献索引：Raenko; Korotkikh; Pekhtereva; Shvaika Russian Journal of Organic Chemistry, 2001 , vol. 37, # 8 p. 1153 - 1157

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被引用次数: 6

摘要

Abstract For the first time is reported on substitution of a hydrogen atom in position 4 of the imidazole ring with an aliphatic substituent occurring in reaction between 1- bromoadamantane and imidazoles. The reaction proceeds alongside the substitution in position 1 at heating in excess imidazole. In o-dichlorobenzene solution adamantylation of benzimidazole afforded 1-(1-adamantyl) benzimidazole and 1, 3-di (1-adamantyl) ...