Cytochalasin support studies. 10. Nucleophilic and electrophilic mercaptanylations via 2-(trimethylsilyl) ethanethiol-derived reagents

…, MG Ranasinghe, JT Palmer, PL Fuchs

文献索引：Anderson, M.B.; Ranasinghe, M.G.; Palmer, J.T.; Fuchs, P.L. Journal of Organic Chemistry, 1988 , vol. 53, # 13 p. 3125 - 3127

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被引用次数: 46

摘要

Summary: 2-(Trimethylsily1) ethanethiol reacts with carboxylic acids, alkyl halides, epoxides, and enones to provide acyl-and alkyl-substituted 2-(trimethylsily1) ethyl sulfides. Electrophilic mercaptanylation is effected by a thiolsulfonate reagent derived from 24trimethylsilyl) ethanethiol.