Bulletin Des Societes Chimiques Belges

Isocyanates bloques: etude cinetique et thermodynamique

I De Aguirre, J Collot

文献索引：Aguirre, I. de; Collot, J. Bulletin des Societes Chimiques Belges, 1989 , vol. 98, # 1 p. 19 - 30

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被引用次数: 17

摘要

Abstract A kinetic and thermodynamic study of the deblocking of urethanes is presented; the blocking agents are phenols, aliphatic alcohols and a polyether. The deblocking occurs via the elimination-addition mechanism. In the transamination reaction, the rate determining step is the amine catalyzed dissociation of the blocked isocyanate. The equilibrium constants of these reactions give the relative stability of blocked isocyanates. The ...