Sequential one-pot bimetallic Ir (III)/Pd (0) catalysed mono-/bis-alkylation and spirocyclisation processes of 1, 3-dimethylbarbituric acid and allenes

…, A Keep, A Derrick, V Sridharan, C Kilner

文献索引：Loefberg, Christian; Grigg, Ronald; Keep, Ann; Derrick, Andrew; Sridharan, Visuvanathar; Kilner, Colin Chemical Communications, 2006 , # 48 p. 5000 - 5002

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被引用次数: 23

摘要

Microwave assisted indirect functionalization of alcohols with 1, 3-dimethylbarbituric acid followed by spirocyclisation employing a sequential one-pot Ir (III)/Pd (0) catalysed process, involving the formation of three new C–C bonds, one spirocyclic ring and one di-or tri- substituted exocyclic alkene, is described.