Kinetic analysis of competitive reactions of isothiocyanates with hydroxyl and alkoxide ions

J Augustín, Š Baláž

文献索引：Augustin, Josef; Balaz, Stefan Collection of Czechoslovak Chemical Communications, 1987 , vol. 52, # 2 p. 443 - 452

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被引用次数: 1

摘要

Abstract The reaction of isothiocyanates with hydroxyl and alkoxide ions has been followed spectrophotometrically in alkaline aqueous-alcoholic solutions. Both the nucleophiles are added to the carbon atom of isothiocyanate group in a competition reaction. The effects of concentration of the nucleophiles, temperature, and acid-base properties of the alcoholic group have been followed on the reaction course. The possibility of analogous reactions ...