Journal of the American Chemical Society

The Course of Addition of Sodium Enol Alkylmalonic Esters to Phenyl Isothiocyanate

J Ross

文献索引：Ross Journal of the American Chemical Society, 1933 , vol. 55, p. 3672,3676

全文：HTML全文

被引用次数: 5

摘要

It has been shown that sodium enol malonic ester adds readily to phenyl isothiocyanate to give the sodium enolate of the monothioanilide of methane tricarboxylic ester. I Ruhemann2 found that on treating this sodium enolate with benzyl chloride, a thiobenzyl ether was obtained, and he considered that this fact supported the original formulation of the addition reaction in which Na-and-CH (COOEt) 2 were written as addendum components. ...