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Tetrahedron

Design and synthesis of new ethylenediamine or propylenediamine diacetic acid derivatives for Re (I) organometallic chemistry

M Allali, E Benoist, N Habbadi, M Gressier, A Souizi…

文献索引:Allali, Mustapha; Benoist, Eric; Habbadi, Nouzha; Gressier, Marie; Souizi, Abdelaziz; Dartiguenave, Michele Tetrahedron, 2004 , vol. 60, # 5 p. 1167 - 1174

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被引用次数: 22

摘要

A general synthetic approach for a novel range of bifunctional chelating agent (BCA) for the 'fac-[M (CO) 3]+'core (M= 99mTc, 99Tc or Re) has been developed. The strategy includes the facile preparation of these tridentate ligands possessing a tertiary amine bearing two carboxylic acid functions as coordinating site and an aromatic amino group for coupling to a biovector. First complexation study has shown that these compounds act exclusively as ...