Canadian journal of chemistry

Protium-deuterium exchange of cyclic and acyclic alkenes in dilute acid medium at elevated temperatures

NH Werstiuk, G Timmins

文献索引：Werstiuk, Nick Henry; Timmins, George Canadian Journal of Chemistry, 1985 , vol. 63, p. 530 - 533

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被引用次数: 22

摘要

A modification of the high temperature-dilute acid (HTDA) method for deuterium labelling of aromatic compounds has been applied to the HD exchange of a number of cyclic and acyclic alkenes. Cyclopentene, cyclohexene, cyclododecene, and tetramethylethylene have been completely exchanged in excellent yield. 1-Methylcyclopentene and 1- methylcyclohexene have also been perdeuterated and cycloheptene and cyclooctene ...