Helvetica Chimica Acta

Cationic palladium (II), platinum (II), and rhodium (I) complexes as acetalisation catalysts

F Gorla, LM Venanzi

文献索引：Gorla, Fabrizio; Venanzi, Luigi M. Helvetica Chimica Acta, 1990 , vol. 73, # 3 p. 690 - 697

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被引用次数: 45

摘要

Abstract The use of [Pd (H 2 O) 2 (Ph 2 PCH 2 CH 2 PPh 2)](CF 3 SO 3) 2 as a catalyst for the acetalisation of a variety of aldehydes and ketones and for trans-acetalisation is described. It is also shown that Pt (H 2 O) 2 (PH 2 PCH 2 CH 2 PPh 2)(CF 3 SO 3) 2 is at least as effective as the corresponding Pd compound, while much lower reaction rates are observed with [Rh (MeOH) 2 (Ph 2 PCH 2 CH 2 PPh 2)][BF 4].