Fluorinated alkoxides. Part XII. Studies on potentially tridentate fluorinated diols; zwitterionic and five-coordinate complexes of Ni2+ and Cu2+

SJ Loeb, JWL Martin, CJ Willis

文献索引：Loeb,S.J. et al. Canadian Journal of Chemistry, 1978 , vol. 56, p. 2369 - 2373

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被引用次数: 8

摘要

The complexing ability towards Ni2+ and Cu2+ of the potentially tridentate ligands HOC (CF3) 2CH2C (O) CH2C (CF3) 2OH, HOC (CF3) 2CH2CH (OH) CH2C (CF3) 2OH, and HOC (CF3) 2CH2CH2N: C (CH3) CH2C (CF3) 2OH has been studied. The first two act as bidentate ligands, uninegative or dinegative according to the extent of ionization of the fluorinated alcohol groups; when both were ionized, the complexes had a zwitterionic ...