Journal of the American Chemical Society

Phosphonitrilic compounds. VIII. Reaction of o-aminophenol with phosphazenes

HR Allcock, RL Kugel

文献索引：R Allcock,H.; Kugel,R.L. Journal of the American Chemical Society, 1969 , vol. 91, p. 5452 - 5456

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被引用次数: 26

摘要

Abstract: o-Aminophenol reacts with a number of halo-and organophosphazenes in boiling xylene to yield bis-(o-phenyleneoxyamino)-2-aminophenoxyphosphorane (111) and ammonium halide or ammonia. This ring cleavage reaction occurs with (NPCIZ)~,(NPCI&,( NPC12) 15, W0,(NPBr&,(NPFJ,, and with certain organocyclotriphosphazenes which contain a five-membered cyclic side unit attached to phosphorus. No reaction was observed with [ ...