Adsorptive and Kinetic Properties on Photocatalytic Hydrogenation of Aromatic Ketones upon UV Irradiated Polycrystalline Titanium Dioxide: Differences between …

S Kohtani, E Yoshioka, K Saito, A Kudo…

文献索引：Kohtani, Shigeru; Yoshioka, Eito; Saito, Kenji; Kudo, Akihiko; Miyabe, Hideto Catalysis Communications, 2010 , vol. 11, # 13 p. 1049 - 1053

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被引用次数: 11

摘要

Adsorptive and kinetic properties on photocatalytic hydrogenation of acetophenone (AP) and 2, 2, 2-trifluoroacetophenone (TFAP) have been investigated upon UV irradiated P25 TiO2 in deaerated ethanol. Kinetic data of AP were analyzed by the Langmuir– Hinschelwood kinetic expression,− d Cs/dt= k max K irr Cs/(1+ AK irr Cs), where k max is the maximum rate and K irr is the apparent adsorption constant under the irradiation. The ...