Oxidation of primary and secondary alcohols by the catalysis of palladium

…, Y Yamada, K Inoue, Y Yamamoto…

文献索引：Tamaru, Yoshinao; Yamada, Yoshimi; Inoue, Kenji; Yamamoto, Youichi; Yoshida, Zen-ichi Journal of Organic Chemistry, 1983 , vol. 48, # 8 p. 1286 - 1292

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被引用次数: 127

摘要

Saturated and unsaturated secondary alcohols are oxidized to the corresponding ketones in good or excellent yields by using an aryl halide (phenyl bromide or mesityl bromide) as an oxidant and palladium (0) or-(II) as a catalyst (0.6-3 mol'% relative to the alcohol) in the presence of a base (NaH or K2C03). The similar oxidation of primary alcohols provides the corresponding aldehydes and/or esters. The aldehyde/ester selectivity is correlated to the ...