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Acylation. I. The Mechanisms of Enol Ester and 1, 3-Diketone Formation in the Reaction of Ketone—Enol Systems with Acyl Halides

WM Muir, PD Ritchie, DJ Lyman

文献索引:Muir,W.M. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 3790 - 3793

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被引用次数: 27

摘要

Several enol benzoates were also shown to with the ratio of products formed being dependent on reaction conditions. yields by acylation of the ketones-base system with enol benzoates. rearrange, in the presence of sodium amide (and absence of ketone), to give 1, 3- diketones.