Dialkoxyethylidene and. eta. 2-1, 2-dialkoxyethylene iron compounds as 2 carbon templates for generating acetaldehyde and a glycolaldehyde ether

EJ Crawford, TW Bodnar, AR Cutler

文献索引：Crawford,E.J.; Bodnar,T.W.; Cutler,A.R. Journal of the American Chemical Society, 1986 , vol. 108, p. 6202

全文：HTML全文

被引用次数: 18

摘要

Conclusions 1. The exothermic reactions of ClCr', CIMn', and ClFe+ with small alkanes in the gas phase have been measured. ClFe'is unreactive. The CI in ClMn'is displaced by alkanes larger than ethane. ClCr+ activates CC and CH bonds of the alkanes leading to ClCr+ alkene products resulting from loss of H2 or CH4. 2. The reactivity of CICr+ is remarkable because Cr+ is unreactive. This is the first example of chemical activation of an unreactive ...