α-Nitro ketone synthesis using N-acylbenzotriazoles

AR Katritzky, AAA Abdel-Fattah…

文献索引：Katritzky, Alan R.; Pastor, Alfredo Journal of Organic Chemistry, 2000 , vol. 65, # 12 p. 3679 - 3681

被引用次数: 29

摘要

Readily available N-acylbenzotriazoles 2a-l (derived from a variety of aliphatic,(hetero) aromatic, and N-protected α-amino carboxylic acids) smoothly convert primary 3a-c and α- functionalized primary nitroalkanes 3d into the corresponding α-nitro ketones 5a-p in yields

~98%

~95%

~76%

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