Tetrahedron

The 'Baylis-Hillman Reaction'mechanism and applications revisited

Y Fort, MC Berthe, P Caubere

文献索引：Fort, Yves; Berthe, Marie Christine; Caubere, Paul Tetrahedron, 1992 , vol. 48, # 31 p. 6371 - 6384

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被引用次数: 122

摘要

It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1, 4-diazabicyclo [2.2. 2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.