Supramolecular Encapsulated Rhodium Catalysts for Branched Selective Hydroformylation of Alkenes at High Temperature

T Besset, DW Norman, JNH Reek

文献索引：Besset, Tatiana; Norman, David W.; Reek, Joost N. H. Advanced Synthesis and Catalysis, 2013 , vol. 355, # 2-3 p. 348 - 352

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被引用次数: 17

摘要

Abstract This study reveals that, in contrast to expectations, supramolecular encapsulated rhodium catalysts can be used at industrially relevant temperatures (75–80 C), providing highly active catalysts. The unprecedented regioselectivity for the branched aldehydes can be retained if high carbon monoxide (CO) concentrations are used.