Ruthenium carbonyl carboxylates with nitrogen containing ligands: IV. Catalytic activity in the hydroformylation of olefins in homogeneous phase

P Frediani, M Bianchi, A Salvini, LC Carluccio…

文献索引：Frediani, Piero; Bianchi, Mario; Salvini, Antonella; Carluccio, Luciano C.; Rosi, Luca Journal of Organometallic Chemistry, 1997 , vol. 547, # 1 p. 35 - 40

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被引用次数: 15

摘要

Ruthenium carbonyl acetato complexes containing bipyridines or phenantrolines ligands are tested as catalysts in the hydroformylation of hex-1-ene in homogeneous phase. These catalysts are active also in solutions containing water and the selectivity to aldehyde is high. Only a moderate hydrogenation of the alkene occurs. The regioselectivity to the linear aldehyde reaches 85.7% when using the mononuclear complex containing 4, 7-dmphen ...