Synthesis of β-d-glucopyranuronosylamine in aqueous solution: kinetic study and synthetic potential

…, RWM Mounguengui, A Peruchon, A Heyraud

文献索引：Ghadban, Ali; Albertin, Luca; Moussavou Mounguengui, Redeo W.; Peruchon, Alexandre; Heyraud, Alain Carbohydrate Research, 2011 , vol. 346, # 15 p. 2384 - 2393

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被引用次数: 5

摘要

A systematic study of the synthesis of β-d-glucopyranuronosylamine in water is reported. When sodium d-glucuronate was reacted with ammonia and/or volatile ammonium salts in water a mixture of β-d-glucopyranuronosylamine and ammonium N-β-d-glucopyranuronosyl carbamate was obtained at a rate that strongly depended on the experimental conditions. In general higher ammonia and/or ammonium salt concentrations led to a faster conversion ...