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Unexpected behavior of the reaction between 1, 2-diaza-1, 3-butadienes and 3-dimethylaminopropenoates: A useful entry to new pyrrolines, pyrroles, and oxazolines

…, A Golobic, B Stanovnik, J Svete

文献索引:Stanovnik, Branko; Svete, Jurij; Tisler, Miha; Zorz, Lilijana; Hvala, Ales; Simonic, Igor Heterocycles, 1988 , vol. 27, # 4 p. 903 - 910

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被引用次数: 22

摘要

We observed a nucleophilic attack by the ene-amino carbon of 3- dimethylaminopropenoates at the terminal carbon of the azo-ene system of 1, 2-diaza-1, 3- butadienes. In tetrahydrofuran at 65° C, this attack produced 1-aminopyrrolines with a high