Unexpected behavior of the reaction between 1, 2-diaza-1, 3-butadienes and 3-dimethylaminopropenoates: A useful entry to new pyrrolines, pyrroles, and oxazolines

…, A Golobic, B Stanovnik, J Svete

Index: Stanovnik, Branko; Svete, Jurij; Tisler, Miha; Zorz, Lilijana; Hvala, Ales; Simonic, Igor Heterocycles, 1988 , vol. 27, # 4 p. 903 - 910

Full Text: HTML

Citation Number: 22

Abstract

We observed a nucleophilic attack by the ene-amino carbon of 3- dimethylaminopropenoates at the terminal carbon of the azo-ene system of 1, 2-diaza-1, 3- butadienes. In tetrahydrofuran at 65° C, this attack produced 1-aminopyrrolines with a high