Reaction of carboxylic acid esters with phenolates in oil-in-water microemulsions based on cetyltrimethylammonium bromide

…, LA Kudryavtseva, NN Vylegzhanina, YF Zuev

文献索引：Mirgorodskaya; Valeeva; Kudryavtseva; Vylegzhanina; Zuev Russian Journal of General Chemistry, 2006 , vol. 76, # 4 p. 590 - 595

全文：HTML全文

被引用次数: 3

摘要

Abstract A kinetic study of reactions of carboxylic acid esters with phenols activated with alkalis or amines in microemulsions based on cationic surfactants showed that the phenolates formed upon activation exhibit different nucleophilicity depending on the value of the negative charge on the oxygen atom, which is determined by the properties of the phenol, ionizing agent, and solvent.