Synthetic Communications®

Facile and Chemoselective Cleavage of Allyl Carboxylic Ester Utilizing NaBH4 in DMSO

BV Pawar, PD Lokhande

文献索引：Pawar, Bharati V.; Lokhande, Pradeep D. Synthetic Communications, 2009 , vol. 39, # 14 p. 2445 - 2453

全文：HTML全文

被引用次数: 0

摘要

Abstract A new method for deprotection of allyl carboxylic ester has been observed by using the inexpensive reagent sodium borohydride in dimethyl sulfoxide (DMSO). Aliphatic and aromatic allyl carboxylic ester undergo deprotection smoothly. The allyl ester group can selectively deprotect better than phenol.