The Journal of Organic Chemistry

Ion radicals. 46. reactions of the adducts of thianthrene and phenoxathiin cation radicals and cyclohexene with nucleophiles

K Iwai, HJ Shine

文献索引：Iwai, Kiyoshi; Shine, Henry J. Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 271 - 276

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被引用次数: 16

摘要

Results% action of the Adduct 2a with Cyanide Ion. This reaction was successful only in dimethyl sulfoxide (MeaO). Many attempts in acetonitrile led only to an almost quantitative yield of thianthrene, that is, as if electron transfer had occurred. The isolated products of reaction in MezSO after 6 h (eq 4) were thianthrene (3, 94%), 1-