Tributylgermanium hydride as a replacement for tributyltin hydride in radical reactions

WR Bowman, SL Krintel, MB Schilling

文献索引：Bowman, W. Russell; Krintel, Sussie L.; Schilling, Mark B. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 4 p. 585 - 592

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被引用次数: 44

摘要

Tributylgermanium hydride (Bu3GeH) can be used as an alternative to tributyltin hydride (Bu3SnH) as a radical generating reagent with a wide range of radical substrates. Tributylgermanium hydride has several practical advantages over tributyltin hydride, eg low toxicity, good stability and much easier work-up of reactions. The reagent can be easily prepared in good yield and stored indefinitely. Suitable substrates include iodides, ...