Tetrahedron

Commutative reduction of aromatic ketones to arylmethylenes/alcohols by hypophosphites catalyzed by Pd/C under biphasic conditions

C Guyon, M Baron, M Lemaire, F Popowycz, E Métay

文献索引：Guyon, Carole; Baron, Marc; Lemaire, Marc; Popowycz, Florence; Metay, Estelle Tetrahedron, 2014 , vol. 70, # 12 p. 2088 - 2095

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被引用次数: 7

摘要

Abstract An efficient method is reported to reduce aromatic ketones selectively into arylmethylenes or alcohols with hypophosphites and Pd/C, depending on the selected conditions. This study could represent a promising alternative to the classical uses of standard hydrides or molecular hydrogen involved in reduction and deoxygenation procedures.