Alcohols and aluminum alkoxides in the presence of Raney nickel as alkylating agents. 3. Reduction of Schiff bases with isopropyl alcohol and aluminum …

…, F De Angelis, A Gambacorta, L Labbiento…

文献索引：Botta, Maurizio; Angelis, Francesco De; Gambacorta, Augusto; Labbiento, Lucia; Nicoletti, Rosario Journal of Organic Chemistry, 1985 , vol. 50, # 11 p. 1916 - 1919

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被引用次数: 1

摘要

The reduction of several N-alkyl and N-aryl ketimines to the corresponding secondary amines is described. The reaction, which generally proceeds in high yield, is effected by isopropyl alcohol and aluminum isopropoxide in the presence of Raney nickel. In the absence of the nickel catalyst, that is, under the Meerwein-Ponndorf-Verley conditions, the reaction takes a different route and N-isopropylamines are formed at preference to the ...