827. Fission of esters of carboxylic acids by boron trichloride

W Gerrard, MA Wheelans

文献索引：Gerrard; Wheelans Journal of the Chemical Society, 1956 , p. 4296,4299

全文：HTML全文

被引用次数: 15

摘要

With the exception of ethyl trichloroacetate, which did not undergo fission, all esters RC0, R'immediately formed a 1: 1 complex with boron trichloride at-80'. Three modes of decomposition were discerned when the complex was heated. When R'was primary, fission