827. Fission of esters of carboxylic acids by boron trichloride

W Gerrard, MA Wheelans

Index: Gerrard; Wheelans Journal of the Chemical Society, 1956 , p. 4296,4299

Full Text: HTML

Citation Number: 15

Abstract

With the exception of ethyl trichloroacetate, which did not undergo fission, all esters RC0, R'immediately formed a 1: 1 complex with boron trichloride at-80'. Three modes of decomposition were discerned when the complex was heated. When R'was primary, fission